Heterobinuclear s‐Indacene Rhodium Complexes: Synthesis and Characterization
Identifieur interne : 004637 ( Main/Exploration ); précédent : 004636; suivant : 004638Heterobinuclear s‐Indacene Rhodium Complexes: Synthesis and Characterization
Auteurs : Christopher Adams [Chili] ; Cesar Morales Erdejo [Chili] ; Ver Nica Morales [Chili] ; Desmond Macleod Arey [Chili] ; Juan Manuel Manríquez [Chili] ; Ivonne Chávez [Chili] ; Alvaro Mu Oz Astro [Chili] ; Fabien Delpech [France] ; Annie Castel [France] ; Heinz Gornitzka [France] ; Monique Rivière Audet [France] ; Pierre Rivière [France] ; Elies Molins [Espagne]Source :
- European Journal of Inorganic Chemistry [ 1434-1948 ] ; 2009-02.
English descriptors
Abstract
The monometallic complexes [Cp*M(2,6‐diethyl‐4,8‐dimethyl‐1‐hydroindacenide)] [M = Fe (1), Ru (2), Co (3)] and the bimetallic species anti‐[Cp*M(2,6‐diethyl‐4,8‐dimethyl‐s‐indacenediide)Rh(η4‐cod)] [M = Fe (4a), Ru (5a), Co (6a)] together with syn‐[Cp*Ru(2,6‐diethyl‐4,8‐dimethyl‐s‐indacenediide)Rh(η4‐cod)] (5b) were synthesized and characterized spectroscopically and in the case of complexes 1 and 5b by X‐ray diffraction. 13C and 103Rh NMR spectroscopic studies suggest that the bonding mode of the rhodium center to the s‐indacenediide ligand can be described as an intermediate between η3‐ and η5‐coordination, but closer to an η3 bonding mode when compared to indenyl–Rh complexes. This result was confirmed by the crystal structure of 5b, as evidenced by the slippage of the rhodium atom towards the periphery of the ligand. Cyclic voltammetry studies revealed intermetallic communication through the fused‐ring ligand exclusively in the cases of 5a and 6a.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
Url:
DOI: 10.1002/ejic.200800920
Affiliations:
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uniqKey="Riviere P" first="Pierre" last="Rivière">Pierre Rivière</name><affiliation wicri:level="4"><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire Hétérochimie Fondamentale et Appliquée, UMR/CNRS 5069, Université Paul Sabatier, 31062 Toulouse, Cedex 9</wicri:regionArea><orgName type="university">Université Toulouse III - Paul Sabatier</orgName><placeName><settlement type="city">Toulouse</settlement><region type="region" nuts="2">Midi-Pyrénées</region></placeName></affiliation></author><author><name sortKey="Molins, Elies" sort="Molins, Elies" uniqKey="Molins E" first="Elies" last="Molins">Elies Molins</name><affiliation wicri:level="1"><country xml:lang="fr">Espagne</country><wicri:regionArea>Instituto de Ciencia de los Materiales de Barcelona (ICMAB‐CSIC), Campus UAB, 08193 Bellaterra, Atalunya</wicri:regionArea><wicri:noRegion>Atalunya</wicri:noRegion></affiliation></author></analytic><monogr></monogr><series><title level="j">European Journal of Inorganic Chemistry</title><title level="j" type="abbrev">Eur. J. Inorg. Chem.</title><idno type="ISSN">1434-1948</idno><idno type="eISSN">1099-0682</idno><imprint><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2009-02">2009-02</date><biblScope unit="volume">2009</biblScope><biblScope unit="issue">6</biblScope><biblScope unit="page" from="784">784</biblScope><biblScope unit="page" to="791">791</biblScope></imprint><idno type="ISSN">1434-1948</idno></series><idno type="istex">AD0B94E29F5BB85FD9D55E01E3D93BA8674AFB66</idno><idno type="DOI">10.1002/ejic.200800920</idno><idno type="ArticleID">EJIC200800920</idno></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">1434-1948</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Bridging ligands</term><term>Cooperative effects</term><term>Heterometallic complexes</term><term>Metal–metal interactions</term></keywords></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The monometallic complexes [Cp*M(2,6‐diethyl‐4,8‐dimethyl‐1‐hydroindacenide)] [M = Fe (1), Ru (2), Co (3)] and the bimetallic species anti‐[Cp*M(2,6‐diethyl‐4,8‐dimethyl‐s‐indacenediide)Rh(η4‐cod)] [M = Fe (4a), Ru (5a), Co (6a)] together with syn‐[Cp*Ru(2,6‐diethyl‐4,8‐dimethyl‐s‐indacenediide)Rh(η4‐cod)] (5b) were synthesized and characterized spectroscopically and in the case of complexes 1 and 5b by X‐ray diffraction. 13C and 103Rh NMR spectroscopic studies suggest that the bonding mode of the rhodium center to the s‐indacenediide ligand can be described as an intermediate between η3‐ and η5‐coordination, but closer to an η3 bonding mode when compared to indenyl–Rh complexes. This result was confirmed by the crystal structure of 5b, as evidenced by the slippage of the rhodium atom towards the periphery of the ligand. Cyclic voltammetry studies revealed intermetallic communication through the fused‐ring ligand exclusively in the cases of 5a and 6a.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)</div></front></TEI><affiliations><list><country><li>Chili</li><li>Espagne</li><li>France</li></country><region><li>Midi-Pyrénées</li></region><settlement><li>Toulouse</li></settlement><orgName><li>Université Toulouse III - Paul Sabatier</li></orgName></list><tree><country name="Chili"><noRegion><name sortKey="Adams, Christopher" sort="Adams, Christopher" uniqKey="Adams C" first="Christopher" last="Adams">Christopher Adams</name></noRegion><name sortKey="Chavez, Ivonne" sort="Chavez, Ivonne" uniqKey="Chavez I" first="Ivonne" last="Chávez">Ivonne Chávez</name><name sortKey="Chavez, Ivonne" sort="Chavez, Ivonne" uniqKey="Chavez I" first="Ivonne" last="Chávez">Ivonne Chávez</name><name sortKey="Macleod Arey, Desmond" sort="Macleod Arey, Desmond" uniqKey="Macleod Arey D" first="Desmond" last="Macleod Arey">Desmond Macleod Arey</name><name sortKey="Manriquez, Juan Manuel" sort="Manriquez, Juan Manuel" uniqKey="Manriquez J" first="Juan Manuel" last="Manríquez">Juan Manuel Manríquez</name><name sortKey="Morales Erdejo, Cesar" sort="Morales Erdejo, Cesar" uniqKey="Morales Erdejo C" first="Cesar" last="Morales Erdejo">Cesar Morales Erdejo</name><name sortKey="Morales, Ver Nica" sort="Morales, Ver Nica" uniqKey="Morales V" first="Ver Nica" last="Morales">Ver Nica Morales</name><name sortKey="Mu Oz Astro, Alvaro" sort="Mu Oz Astro, Alvaro" uniqKey="Mu Oz Astro A" first="Alvaro" last="Mu Oz Astro">Alvaro Mu Oz Astro</name></country><country name="France"><region name="Midi-Pyrénées"><name sortKey="Delpech, Fabien" sort="Delpech, Fabien" uniqKey="Delpech F" first="Fabien" last="Delpech">Fabien Delpech</name></region><name sortKey="Castel, Annie" sort="Castel, Annie" uniqKey="Castel A" first="Annie" last="Castel">Annie Castel</name><name sortKey="Delpech, Fabien" sort="Delpech, Fabien" uniqKey="Delpech F" first="Fabien" last="Delpech">Fabien Delpech</name><name sortKey="Gornitzka, Heinz" sort="Gornitzka, Heinz" uniqKey="Gornitzka H" first="Heinz" last="Gornitzka">Heinz Gornitzka</name><name sortKey="Riviere Audet, Monique" sort="Riviere Audet, Monique" uniqKey="Riviere Audet M" first="Monique" last="Rivière Audet">Monique Rivière Audet</name><name sortKey="Riviere, Pierre" sort="Riviere, Pierre" uniqKey="Riviere P" first="Pierre" last="Rivière">Pierre Rivière</name></country><country name="Espagne"><noRegion><name sortKey="Molins, Elies" sort="Molins, Elies" uniqKey="Molins E" first="Elies" last="Molins">Elies Molins</name></noRegion></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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